Faraday constant
In physics and chemistry, the Faraday constant (named after Michael Faraday) is the magnitude of electric charge per mole of electrons.[1] The Faraday constant, denoted F, is widely used in calculations in electrochemistry, and has the currently accepted value:[2]
- F = 96 485.3399(24) C/mol
The constant F has a simple relation to two other physical constants:
- F = Ne
where NA is the Avogadro constant (approximately 6.02 mol?1) and e is the elementary charge, the magnitude of the charge on an electron (approximately 1.602 C). This relation is true because the amount of charge of a mole of electrons is equal to the amount of charge in one electron, multiplied by the number of electrons in a mole.
The value of F was first determined by weighing the amount of silver deposited in an electrochemical reaction in which a measured current was passed for a measured time, and using Faraday's law of electrolysis.[3] Research is continuing into more accurate ways of determining the interrelated constants F, NA, and e.
See also
References
- ↑ The term "magnitude" is used in the sense of "absolute value": The charge of an electron is negative, but F is always defined to be positive.
- ↑ CODATA 2006
- ↑ NIST Introduction to physical constants
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