Energy storage

Energy storage is the storing of some form of energy that can be drawn upon at a later time to perform some useful operation. A device that stores energy is sometimes called an accumulator. All forms of energy are either potential energy (eg. chemical, gravitational or electrical energy) or kinetic energy (eg. thermal energy). A wind up clock stores potential energy (in this case mechanical, in the spring tension), a battery stores readily convertible chemical energy to keep a clock chip in a computer running (electrically) even when the computer is turned off, and a hydroelectric dam stores power in a reservoir as gravitational potential energy. Even food is a form of energy storage, chemical in this case.

History

Energy storage as a natural process is as old as the universe itself - the energy present at the initial creation of the Universe has been stored in stars such as the Sun, and is now being used by humans directly (e.g. through solar heating), or indirectly (e.g. by growing crops or conversion into electricity in solar cells). Energy storage systems in commercial use today can be broadly categorized as mechanical, electrical, chemical, biological, thermal and nuclear.

As a purposeful activity, energy storage has existed since pre-history, though it was often not explicitly recognized as such. An example of deliberate mechanical energy storage is the use of logs or boulders as defensive measures in ancient forts - the logs or boulders were collected at the top of a hill or wall, and the energy thus stored used to attack invaders who came within range.

A more recent application is the control of waterways to drive water mills for processing grain or powering machinery. Complex systems of reservoirs and dams were constructed to store and release water (and the potential energy it contained) when required.

Energy storage became a dominant factor in economic development with the widespread introduction of electricity and refined chemical fuels, such as gasoline, kerosene and natural gas in the late 1800s. Unlike other common energy storage used in prior use, such as wood or coal, electricity must be used as it is generated and cannot be stored on anything other than a minor scale. Electricity is transmitted in a closed circuit, and for essentially any practical purpose cannot be stored as electrical energy. This meant that changes in demand could not be accommodated without either cutting supplies (eg, via brownouts or blackouts) or arranging for a storage technique.

An early solution to the problem of storing energy for electrical purposes was the development of the battery, an electrochemical storage device. It has been of limited use in electric power systems due to small capacity and high cost. A similar possible solution with the same type of problems is the capacitor.

Chemical fuels have become the dominant form of energy storage, both in electrical generation and energy transportation. Chemical fuels in common use are processed coal, gasoline, diesel fuel, natural gas, liquefied petroleum gas (LPG), propane, butane, ethanol, biodiesel and hydrogen. All of these chemicals are readily converted to mechanical energy and then to electrical energy using heat engines (turbines or other internal combustion engines, or boilers or other external combustion engines) used for electrical power generation. Heat engine powered generators are nearly universal, ranging from small engines producing only a few kilowatts to utility-scale generators with ratings up to 800 megawatts.

Electrochemical devices called fuel cells were invented about the same time as the battery. However, for many reasons, fuel cells were not well developed until the advent of manned spaceflight (the Gemini Program) when lightweight, non-thermal (ie, efficient) sources of electricity were required in spacecraft. Fuel cell development has increased in recent years to an attempt to increase conversion efficiency of chemical energy stored in hydrocarbon or hydrogen fuels into electricity.

At this time, liquid hydrocarbon fuels are the dominant forms of energy storage for use in transportation. However, these produce greenhouse gases when used to power cars, trucks, trains, ships and aircraft. Carbon-free energy carriers, such as hydrogen, or carbon-neutral energy carriers, such as some forms of ethanol or biodiesel, are being sought in response to concerns about the possible consequences of greenhouse gas emissions.

Some areas of the world (Washington and Oregon in the USA, and Wales in the United Kingdom are examples) have used geographic features to store large quantities of water in elevated reservoirs, using excess electricity at times of low demand to pump water up to the reservoirs, then letting the water fall through turbine generators to retrieve the energy when demand peaks.

Several other technologies have also been investigated, such as flywheels or compressed air storage in underground caverns, but to date no widely available solution to the challenge of mass energy storage has been deployed commercially.

Grid energy storage

The upper reservoir (Llyn Stwlan) and dam of the Ffestiniog Pumped Storage Scheme in north Wales. The lower power station has four water turbines which generate 360 MW of electricity within 60 seconds of the need arising. The size of the dam can be judged from the car parked below.

Storage methods

Hydrogen

Hydrogen is also being developed as an electrical power storage medium. Hydrogen is not a primary energy source, but a portable energy storage method, because it must first be manufactured by other energy sources in order to be used. However, as a storage medium, it may be a significant factor in using renewable energies. See hydrogen storage. Hydrogen may be used in conventional internal combustion engines, or in fuel cells which convert chemical energy directly to electricity without flames, similar to the way the human body burns fuel. The hydrogen production requires either reforming natural gas with steam, or, for a possibly renewable and more ecologic source, the electrolysis of water into hydrogen and oxygen. The former process has carbon dioxide as a by-product. With high pressure electrolysis, the greenhouse burden depends on the source of the power.

With intermittent renewables such as solar and wind, the output may be fed directly into an electricity grid. At penetrations below 20% of the grid demand, this does not severely change the economics; but beyond about 20% of the total demand, external storage will become important. If these sources are used for electricity to make hydrogen, then they can be utilized fully whenever they are available, opportunistically. Broadly speaking, it does not matter when they cut in or out, the hydrogen is simply stored and used as required. A community based pilot program using wind turbines and hydrogen generators is being undertaken from 2007 for five years in the remote community of Ramea, Newfoundland and Labrador.^[2] A similar project has been going on since 2004 on Utsira, a small Norwegian island municipality.

Nuclear advocates note that using nuclear power to manufacture hydrogen would help solve plant inefficiencies. Here the plant would be run continuously at full capacity, with perhaps all the output being supplied to the grid in peak periods, and any not needed to meet demand being used to make hydrogen at other times. This would mean far better efficiency for the nuclear power plants. High temperature (950-1,000�C) gas cooled nuclear generation IV reactors have the potential to separate hydrogen from water by thermochemical means using nuclear heat as in the sulfur-iodine cycle.

The efficiency for hydrogen storage is typically 50 to 60% overall, which is lower than pumped storage systems or batteries. About 50 kWh (180 MJ) is required to produce a kilogram of hydrogen by electrolysis, so the cost of the electricity clearly is crucial, even for hydrogen uses other than storage for electrical generation. At $0.03/kWh, common off-peak high-voltage line rate in the U.S., this means hydrogen costs $1.50 a kilogram for the electricity, equivalent to $1.50 a US gallon for gasoline if used in a fuel cell vehicle. Other costs would include the electrolyzer plant, hydrogen compressors or liquefaction, storage and transportation, which will be significant.

Biofuels

Various biofuels such as biodiesel, straight vegetable oil, alcohol fuels, or biomass can be used to replace hydrocarbon fuels. Various chemical processes can convert the carbon and hydrogen in coal, natural gas, plant and animal biomass, and organic wastes into short hydrocarbons suitable as replacements for existing hydrocarbon fuels. Examples are Fischer-Tropsch diesel, methanol, dimethyl ether, or syngas. This diesel source was used extensively in World War II in Germany, with limited access to crude oil supplies. Today South Africa produces most of country's diesel from coal for similar reasons.^[4] A long term oil price above 35 USD may make such synthetic liquid fuels economical on a large scale (See coal). Some of the energy in the original source is lost in the conversion process. Historically, coal itself has been used directly for transportation purposes in vehicles and boats using steam engines. And compressed natural gas is being used in special circumstances fuel, for instance in busses for some mass transit agencies.

Synthetic hydrocarbon fuel

Carbon dioxide in the atmosphere has been, experimentally, converted into hydrocarbon fuel with the help of energy from another source. To be useful industrially, the energy will probably have to come from sunlight using, perhaps, future artificial photosynthesis technology.^[5]^[6] Another alternative for the energy is electricity or heat from solar energy or nuclear power.^[7]^[8] Compared to hydrogen, many hydrocarbon fuels have the advantage of being immediately usable in existing engine technology and existing fuel distribution infrastructures. Manufacturing synthetic hydrocarbon fuel reduces the amount of carbon dioxide in the atmosphere until the fuel is burned, when the same amount of carbon dioxide returns to the atmosphere. If usable on a wide scale, this approach may help in the long term to avoid some of the deleterious effects of greenhouse gas emission.

Methane

Methane is the simplest hydrocarbon with the molecular formula CH₄. Methane could be produced from electricity of renewable energies. Methane can be stored more easily than hydrogen and the transportation, storage and combustion infrastructure are mature (pipelines, gasometers, power plants).

Methane would be stored and used to produce electricity later. Produced water would be recycled back to the electrolysis stage, reducing the need for new pure water. In the electrolysis stage oxygen would also be stored for methane combustion in a pure oxygen environment in an adjacent power plant, eliminating e.g. nitrogen oxides. In the combustion of methane, carbon dioxide and water are produced.

Produced carbon dioxide would be recycled back to boost the Sabatier process and water would be recycled back to the electrolysis stage. The carbon dioxide produced by methane combustion would be turned back to methane, thus producing no greenhouse gases. Methane production, storage and adjacent combustion would recycle all the reaction products, creating a cycle.

Boron, silicon, and zinc

Mechanical storage

Energy can be stored in water pumped to a higher elevation, in compressed air, or in spinning flywheels.

Compressed air energy storage technology stores low cost off-peak energy, in the form of compressed air in an underground reservoir. The air is then released during peak load hours and heated with the exhaust heat of a standard combustion turbine. This heated air is converted to energy through expansion turbines to produce electricity. A CAES plant has been in existence in McIntosh, Alabama since 1991 and has run successfully.

Several companies have done preliminary design work for vehicles using compressed air power.^[12]^[13]

Intermittent power

Many renewable energy systems produce intermittent power. Other generators on the grid can be throttled to match varying production from renewable sources, but most of the existing throttling capacity is already committed to handling load variations. Further development of intermittent renewable power will require some combination of grid energy storage, demand response, and spot pricing. Intermittent energy sources is limited to at most 20-30% of the electricity produced for the grid without such measures. If electricity distribution loss and costs are managed, then intermittent power production from many different sources could increase the overall reliability of the grid.

Non-intermittent renewable energy sources include hydroelectric power, geothermal power, solar thermal, tidal power, Energy tower, ocean thermal energy conversion, high altitude airborne wind turbines, biofuel, and solar power satellites. Solar photovoltaics, although technically intermittent, produce electricity largely during peak periods (ie, daylight), and hence do reduce the need for peak power generation, though somewhat unreliably in most areas since weather conditions interfere with terrestrially mounted solar cells.

On the demand side, demand response programs, which send market pricing signals to consumers (or their equipment), can be a very effective way of managing variations in electricity production. For example, electrically powered hydrogen production can be set to increase when electricity is being produced beyond current demand (and prices will be lowest), and conversely, hot water heaters can be automatically set to a lower temperature when demand is high and pricing is also high.